martes, 8 de julio de 2014

Copolymer Composition Deviations from Mayo–Lewis Conventional Free Radical Behavior in Nitroxide Mediated Copolymerization

Macromolecular Theory and Simulation, mayo de 2014

Thumbnail image of graphical abstract

Artículo de portada

Composition deviations from the Mayo-Lewis behavior can be found in nitroxide mediated copolymerizations, which can be understood as arising from competitive equilibria represented by characteristic differences δXY, as explained in the paper. As illustrated in the picture, these deviations can be attenuated using an additional source of radicals. Copolymerization conditions that maximize or minimize these deviations are reported. Further details can be found in the article by I. Zapata-González, R. A. Hutchinson, K. Matyjaszewski, E. Saldívar-Guerra,* and J. Ortiz-Cisneros on page 245.


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